Amorphous silicon

Amorphous silicon (a-Si) is the non-crystalline form of silicon used for solar cells and thin-film transistors in LCDs. Used as semiconductor material for a-Si solar cells, or thin-film silicon solar cells, it is deposited in thin films onto a variety of flexible substrates, such as glass, metal and plastic. Amorphous silicon cells generally feature low efficiency. As a second-generation thin-film solar cell technology, amorphous silicon was once expected to become a major contributor in the fast-growing worldwide photovoltaic market, but has since lost its significance due to strong competition from conventional crystalline silicon cells and other thin-film technologies such as CdTe and CIGS.[citation needed] Amorphous silicon is a preferred material for the thin film transistor (TFT) elements of liquid crystal displays (LCDs) and for x-ray imagers. Amorphous silicon differs from other allotropic variations, such as monocrystalline silicon—a single crystal, and polycrystalline silicon, that consists of small grains, also known as crystallites.

FAQ


1. What are the Amorphous materials used as a variant of thin-film cells? Amorphous materials are solids without long-range orders. Due to the absence of these orders, these materials are difficult to analyse and study, unlike crystalline materials.
2. What is the fundamental difference between polycrystalline and amorphous silicon solar cells? The primary difference between polycrystalline and amorphous is that the former has a long-range order, whereas the latter doesn’t.
3. Do amorphous silicon solar panels require a lot of space to accommodate? No, the amorphous silicon solar panels do not require a lot of space to accommodate. Unlike monocrystalline and polycrystalline silicon solar panels, they can easily fit in small sizes.

Product Description

Silicon is a fourfold coordinated atom that is normally tetrahedrally bonded to four neighboring silicon atoms. In crystalline silicon (c-Si) this tetrahedral structure continues over a large range, thus forming a well-ordered crystal lattice. In amorphous silicon this long range order is not present. Rather, the atoms form a continuous random network. Moreover, not all the atoms within amorphous silicon are fourfold coordinated. Due to the disordered nature of the material some atoms have a dangling bond. Physically, these dangling bonds represent defects in the continuous random network and may cause anomalous electrical behavior. The material can be passivated by hydrogen, which bonds to the dangling bonds and can reduce the dangling bond density by several orders of magnitude. Hydrogenated amorphous silicon (a-Si:H) has a sufficiently low amount of defects to be used within devices such as solar photovoltaic cells, particularly in the protocrystalline growth regime Monocrystalline solar panels usually have the highest efficiency and power capacity out of all types of solar panels. Monocrystalline panel efficiencies can range from 17% to 20%. Because monocrystalline solar cells are made out of a single crystal of silicon, electrons can flow easier through the cell, which makes the PV cell efficiency higher than other types of solar panels. The higher efficiency of monocrystalline solar panels means that they require less space to reach a given power capacity. So, monocrystalline solar panels will usually have a higher power output rating than either polycrystalline or thin-film modules.

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