Cadmium telluride

CdTe solar cells are the second most common photovoltaic (PV) technology in the world marketplace after crystalline silicon, currently representing 5% of the world market. CdTe thin-film solar cells can be manufactured quickly and inexpensively, providing an alternative to conventional silicon-based technologies. The record efficiency for a laboratory CdTe solar cell is 22.1% by First Solar. First Solar also reported its average commercial module efficiency to be approximately 18% at the end of 2020.

BENEFITS


1. High absorption: Cadmium telluride is a direct-bandgap material with bandgap energy that can be tuned from 1.4 to 1.5 (eV), which is nearly optimal for converting sunlight into electricity using a single junction.
2. Low-cost manufacturing: Cadmium telluride solar cells use high throughput manufacturing methods to produce completed modules from input materials in a matter of hours.
Production
The most common CdTe solar cells consist of a p-n heterojunction structure containing a p-doped CdTe layer matched with an n-doped cadmium sulfide (CdS) or magnesium zinc oxide (MZO) window layer. Typical CdTe thin-film deposition techniques include vapor-transport deposition and close-spaced sublimation. CdTe absorber layers are generally grown on top of a high-quality transparent conductive oxide (TCO) layer—usually fluorine-doped tin oxide (SnO2:F). Cells are completed using a back electrical contact—typically a layer of zinc telluride (ZnTe) followed by a metal layer or a carbon paste that also introduces copper (Cu) into the rear of the cell.

Product Description

The United States is the leader in cadmium telluride (CdTe) photovoltaic (PV) manufacturing, and NREL has been at the forefront of research and development in this area. PV solar cells based on CdTe represent the largest segment of commercial thin-film module production worldwide. Recent improvements have matched the efficiency of multicrystalline silicon while maintaining cost leadership.
CdTe-based PV is considered a thin-film technology because the active layers are just a few microns thick, or about a tenth the diameter of a human hair. A schematic of a typical CdTe solar cell is shown here. Transparent conducting oxide (TCO) layers such as SnO2 or Cd2SnO4 are transparent to visible light and highly conductive to transport current efficiently. Intermediate layers such as CdS help in both the growth and electrical properties between the TCO and CdTe. The CdTe film acts as the primary photoconversion layer and absorbs most visible light within the first micron of material. Together, the CdTe, intermediate, and TCO layers form an electric field that converts light absorbed in the CdTe layer into current and voltage. Metal is placed on the back to form electrical contacts. In production, all these layers are deposited on incoming glass and processed into complete solar panels in just a few hours.

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